
Mark Orazem
Distinguished Professor University of Florida
- Gainesville FL
Mark Orazem studies corrosion, batteries, fuel cells, sensors, and electrodes for neural stimulation.
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Articles
Analysis of electrochemical impedance spectroscopy data for sputtered iridium oxide electrodes
IOP ScienceLutz, et al.
2025-05-07
Our objective was to perform a complete analysis of in-vitro impedance data for sputtered iridium oxide film (SIROF) micro-electrodes. An interpretation model was developed that considered the impedance of the bare surface and the contribution of a porous component, based on the de Levie model of porous electrodes.
On the Proper Use of a Warburg Impedance
Journal of The Electrochemical SocietyMark E. Orazem, et. al
2024-04-17
Recent battery papers commonly employ interpretation models for which diffusion impedances are in series with interfacial impedance. The models are fundamentally flawed because the diffusion impedance is inherently part of the interfacial impedance.
Comparison of Approaches for Assessing Linearity of Impedance Measurements
Journal of The Electrochemical SocietyJie Min Goh, et. al
2024-03-28
Electrochemical impedance spectroscopy experiments are inherently nonlinear for systems affected by faradaic reactions. The methods used to determine whether an experiment is sufficiently linear include observation of current as a function of potential, known as Lissajous plots, measurement of total harmonic distortion, and post-experiment assessment of consistency with the Kramers–Kronig relations.